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Synthesis of mono and bis-4-methylpiperidiniummethyl-urea as corrosion inhibitors for steel in acidic

Abbas TEIMOURI, Nasrin SOLTANI, Alireza Najafi CHERMAHINI

《化学科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 43-50 doi: 10.1007/s11705-010-0532-7

摘要： Mono and bis-4-methylpiperidiniummethyl urea were synthesized, characterized and used as new corrosion inhibitors of mild steel in the acidic media. Inhibitory effect of two compounds on mild steel surface in the 1 mol·L sulphuric acid has been studied by a series of techniques, such as potentiodynamic polarization, weight loss and quantum chemical calculation methods. Potentiodynamic polarization measurements showed that two inhibitors are mixed type. All measurements showed that inhibition efficiencies enhanced with increase of inhibitor concentration. This reveals that inhibitive actions of inhibitors were mainly due to adsorption on mild steel surface. Density functional (DFT) calculations have been carried out for the title compounds by performing HF and DFT levels of theory using the standard 6-31G* basis set.

关键词： corrosion inhibitors     mild steel     acidic medium     theoretical studies     DFT    

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Removing ammonia from air with a constant pH, slightly acidic water　spray wet scrubber using recycled

Ahmad Kalbasi Ashtari, Amir M. Samani Majd, Gerald L. Riskowski, Saqib Mukhtar, Lingying Zhao

《环境科学与工程前沿（英文）》 2016年 第10卷 第6期 doi: 10.1007/s11783-016-0869-3

摘要： Slightly acidic solutions are a practical means of removing ammonia from air Scrubbed NH accumulates in solution as NH and should be an excellent fertilizer Increased air velocity decreased NH removal and increased NH collection Previous research on wet scrubbers has only studied highly acidic scrubbing solutions because of their high ammonia capture efficiencies; however, the high acidity created practical problems. Lower acidity solutions would reduce corrosion, maintenance, and cost; however, designers may need to use strategies for increasing scrubber effectiveness, such as using lower air velocities. The objective of this study was to determine if a spray scrubber with slightly acidic and higher pH scrubbing solution (pH from 2 to 8) could effectively remove NH from NH laden air (such as animal building exhaust air), and also collect this valuable resource for later use as a fertilizer. A bench-scale spray wet scrubber treated 20 ppmv NH /air mixture in a countercurrent contact chamber. First, the solution pH was varied from 2 to 8 while maintaining constant air velocity at 1.3 m·s . Next, air velocity was increased (2 and 3 m·s ) while solution pH remained constant at pH6. At 1.3 m·s , NH removal efficiencies ranged between 49.0% (pH8) and 84.3% (pH2). This study has shown that slightly acidic scrubbing solutions are a practical means of removing ammonia from air especially if the scrubber is designed to increase collisions between solution droplets and NH molecules. The NH removed from the air was held in solution as NH and accumulates over time so the solution should be an excellent fertilizer.

关键词： Ammonia     Spray wet scrubber     Slightly acidic scrubbing solution     Controlled pH     Removal efficiency    

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Effective and selective separation of perrhenate from acidic wastewater by super-stable, superhydrophobic

《环境科学与工程前沿（英文）》 2022年 第16卷 第2期 doi: 10.1007/s11783-021-1456-9

摘要：

• A ZnO-biochar hybrid composite was prepared by solvothermal-pyrolysis synthesis.

关键词： Selectivity     Adsorption     Re(VII)     ZnO     Biochar    

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A pyrazine based metal-organic framework for selective removal of copper from strongly acidic solutions

《环境科学与工程前沿（英文）》 2023年 第17卷 第3期 doi: 10.1007/s11783-023-1633-0

摘要：

● pz-UiO-66 was synthesized facilely by a solvothermal method.

关键词： Pyrazine     Metal-organic frameworks     Copper removal     Strong acidity     High selectivity    

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大中功率节能调速传动的合理电压等级

马小亮

《中国工程科学》 2001年 第3卷 第11期   页码 80-84

摘要：

大中功率风机和泵采用变频调速可节约大量电能，大部分功率在0.2～2 MW范围中。我国现在200 kW以上的电机多是中压，现行中压电网多为10 kV，选用10 kV直接变频从技术和经济角度看都不太合理。由于变频器输入侧都有变压器，因此电机和变频器没有必要和电网一致。文章讨论不同功率段的合理电压等级以及在电机电压和电网电压不同情况下当变频器出现故障时如何实现旁路工作。

关键词： 大中功率     节能调速     合理电压等级     低压变频     中压变频     旁路    

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Uncoupled state space solution to layered poroelastic medium with anisotropic permeability and compressible

Zhiyong AI, Wenze ZENG, Yichong CHENG, Chao WU

《结构与土木工程前沿（英文）》 2011年 第5卷 第2期   页码 171-179 doi: 10.1007/s11709-011-0103-0

摘要： This paper presents an uncoupled state space solution to three-dimensional consolidation of layered poroelastic medium with anisotropic permeability and compressible pore fluid. Starting from the basic equations of poroelastic medium, and introducing intermediate variables, the state space equation usually comprising eight coupled state vectors is uncoupled into two sets of equations of six and two state vectors in the Laplace-Fourier transform domain. Combined with the continuity conditions between adjacent layers and boundary conditions, the uncoupled state space solution of a layered poroelastic medium is obtained by using the transfer matrix method. Numerical results show that the anisotropy of permeability and the compressibility of pore fluid have remarkable influence on the consolidation behavior of poroelastic medium.

关键词： uncoupled state space solution     layered poroelastic medium     three-dimensional consolidation     anisotropic permeability     compressible pore fluid    

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nsted acidic ionic liquids

Xiaomeng WANG, Mingjuan HAN, Hui WAN, Cao YANG, Guofeng GUAN

《化学科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 107-112 doi: 10.1007/s11705-010-0539-0

摘要： Br?nsted acidic ionic liquids (ILs), -methylimidazole hydrogen sulfate ([HMIm]HSO ) and -methylpyrrolidone hydrogen sulfate ([HNMP]HSO ), are synthesized and employed as extractants to extract thiophene from model gasoline (thiophene dissolved in -octane). The effect of extraction temperature, extraction time and volume ratio of ILs to model gasoline on desulfurization rates is investigated. Then, the optimal desulfurization conditions are obtained: the ratio of ILs to model gasoline is 1∶1, extraction temperature is 50°C for [HMIm]HSO and 60°C for [HNMP]HSO , extraction time is 60 min. Meanwhile, the desulfurization rate of [HNMP]HSO for model gasoline is 62.8%, which is higher than that of [HMIm]HSO (55.5%) under optimal conditions. The reason is discussed on the basis of the interaction energy between thiophene and ILs at the B3LYP/6-311++ G(d,p) level. Furthermore, the total desulfurization rate of [HNMP]HSO and [HMIm]HSO reaches 96.4% and 94.4%, respectively, by multistage extraction. Finally, the used ILs can be reused by vacuum drying, and their desulfurization rates are not significantly decreased after recycling 7 times in single-stage desulfurization.

关键词： br?nsted ionic liquids     model gasoline     thiophene     extraction     density functional theory    

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Improved CO

Mahboube Ghahramaninezhad, Fatemeh Mohajer, Mahdi Niknam Shahrak

《化学科学与工程前沿（英文）》 2020年 第14卷 第3期   页码 425-435 doi: 10.1007/s11705-019-1873-5

摘要： Post-synthetic functionalization or modification has been regarded as a promising strategy to treat surfaces of adsorbents for their applications in targeted adsorption and separation processes. In this work, a novel microporous adsorbent for carbon capturing was developed via functionalization of zeolitic imidazolate framework-91 (ZIF-91) to generate a hard/hard (metal-oxygen) structure named as lithium-modified ZIF-91 (ZIF-91-OLi compound). To this purpose, the ZIF-91 compound as an intermediate product was achieved by reduction of ZIF-90 in the presence of NaBH as a good reducing agent. Afterwards, acidic hydrogen atoms in the hydroxyl groups of ZIF-91 were exchanged with lithium cations via reaction of -BuLi compound as an organo lithium agent through an appropriate procedure. In particular, the as-synthesized ZIF-91-OLi operated as an excellent electron-rich center for CO adsorption through trapping the positive carbon centers in the CO molecule. DFT calculations revealed that the presence of lithium over the surface of ZIF-91-OLi adsorbent plays an effective role in double enhancement of CO storage via creating a strong negative charge center at the oxygen atoms of the imidazolate linker as a result of the lithium/hydrogen exchange system. Finally, the selectivity of CO /N was investigated at different temperatures, revealing the ZIF-91-OLi as a selective adsorbent for industrial application.

关键词： hard/hard structure     acidic hydrogen     ZIF-91     carbon capture     ZIF-91-OLi    

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Preparation of solar selective absorbing CuO coating for medium temperature application

HUANG Qunwu, WANG Yiping, LI Jinhua

《化学科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 256-260 doi: 10.1007/s11705-007-0046-0

摘要： A new method of preparing CuO solar selective absorbing coating for medium temperature is presented. After pretreatment, brass was overlaid with CuO by chemical plating. The effects of reactant concentration, reaction temperature and reaction time on the absorptivity of CuO coating were investigated. The optimized condition of preparing CuO coating was obtained. The CuO coating was analyzed with X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). In order to prolong the period of use, the CuO coating was protected by TiO. The experiment shows that the TiO/CuO coating is more heat-resistant, acid-resistant, and wear resistant than CuO coating, without losing absorptivity markedly. The TiO coating can reduce emissivity and protect the CuO coating.

关键词： photoelectron spectroscopy     temperature     pretreatment     absorptivity     microscopy    

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Selective removal of iron(III) from highly salted chloride acidic solutions by solvent extraction using

Guoping Hu, Yue Wu, Desheng Chen, Yong Wang, Tao Qi, Lina Wang

《化学科学与工程前沿（英文）》 2021年 第15卷 第3期   页码 528-537 doi: 10.1007/s11705-020-1955-4

摘要： Metal ions including Fe , Ca , Mg , Ni , Co and Cu are commonly found in the leaching solution of laterite-nickel ores, and the pre-removal of Fe is extremely important for the recovery of nickel and cobalt. Di(2-ethylhexyl)phosphate acid (D2EHPA) showed high extraction rate and selectivity of Fe over other metal ions. The acidity of the aqueous solution is crucial to the extraction of Fe , and the stoichiometry ratio between Fe and the extractant is 0.86:1.54. The enthalpy for the extraction of Fe using D2EHPA was 19.50 kJ/mol. The extraction of Fe was ≥99% under the optimized conditions after a three-stage solvent extraction process. The iron stripping effects of different reagents showed an order of H C O >NH HCO >HCl>NaCl>NaHCO >Na SO . The stripping of Fe was ≥99% under the optimized conditions using H C O as a stripping reagent.

关键词： solvent extraction     iron     di(2-ethylhexyl)phosphate acid     separation    

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Frontier of continuous structural health monitoring system for short & medium span bridges and condition

Ayaho MIYAMOTO, Risto KIVILUOMA, Akito YABE

《结构与土木工程前沿（英文）》 2019年 第13卷 第3期   页码 569-604 doi: 10.1007/s11709-018-0498-y

摘要： It is becoming an important social problem to make maintenance and rehabilitation of existing short and medium span(10-20 m) bridges because there are a huge amount of short and medium span bridges in service in the world. The kernel of such bridge management is to develop a method of safety(condition) assessment on items which include remaining life and load carrying capacity. Bridge health monitoring using information technology and sensors is capable of providing more accurate knowledge of bridge performance than traditional strategies. The aim of this paper is to introduce a state-of-the-art on not only a rational bridge health monitoring system incorporating with the information and communication technologies for lifetime management of existing short and medium span bridges but also a continuous data collecting system designed for bridge health monitoring of mainly short and medium span bridges. In this paper, although there are some useful monitoring methods for short and medium span bridges based on the qualitative or quantitative information, mainly two advanced structural health monitoring systems are described to review and analyse the potential of utilizing the long term health monitoring in safety assessment and management issues for short and medium span bridge. The first is a special designed mobile loading device(vehicle) for short and medium span road bridges to assess the structural safety(performance) and derive optimal strategies for maintenance using reliability based method. The second is a long term health monitoring method by using the public buses as part of a public transit system (called bus monitoring system) to be applied mainly to short and medium span bridges, along with safety indices, namely, “characteristic deflection” which is relatively free from the influence of dynamic disturbances due to such factors as the roughness of the road surface, and a structural anomaly parameter.

关键词： condition assessment     short & medium span bridge     structural health monitoring(SHM)     long-term data collection     system     maintenance     bridge performance     information technology     loading vehicle(public bus)     in-situ loading    

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大中型水利工程建设管理的实践和体会

张基尧

《中国工程科学》 2011年 第13卷 第8期   页码 22-25

摘要： 水利工程建设是基础设施建设的重要组成部分。加强水利工程建设管理是提高水利投资效益和社会、经济、生态效益的重要途经，是工程管理科学研究的重要内容。文章主要阐述了不同阶段大中型水利工程建设管理的责任主体、管理重点、有效做法和成功案例。

关键词： 大中型水利工程；项目管理；实践体会    

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Electrolyzed water and its application in animal houses

Weichao ZHENG,Li NI,Baoming LI

《农业科学与工程前沿（英文）》 2016年 第3卷 第3期   页码 195-205 doi: 10.15302/J-FASE-2016109

摘要： Electrolyzed water (EW) can be produced by electrolysis of a dilute salt solution. Slightly acidic electrolyzed water (SAEW, pH 5.0–6.5) and neutral electrolyzed water (NEW, pH 6.5–8.5) are considered healthy and environmentally friendly because no hazardous chemicals are added in its production, there is reduced corrosion of surfaces and it minimizes the potential for damage to animal and human health. Over the last decade, EW has become increasingly popular as an alternative disinfectant for decontamination in animal houses. However, there have been some issues related to EW that are not well known, including different mechanisms for generation of SAEW and NEW, and the antimicrobial mechanism of EW. This review covers the definitions of SAEW and NEW, different generation systems for SAEW and NEW, the antimicrobial mecha- nism of EW, and recent developments related to the application of SAEW and NEW in animal houses.

关键词： disinfection     poultry and livestock     slightly acidic electrolyzed water     neutral electrolyzed water    

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Liquid metal as energy transportation medium or coolant under harsh environment with temperature below

Yunxia GAO, Lei WANG, Haiyan LI, Jing LIU

《能源前沿（英文）》 2014年 第8卷 第1期   页码 49-61 doi: 10.1007/s11708-013-0285-3

摘要： The current highly integrated electronics and energy systems are raising a growing demand for more sophisticated thermal management in harsh environments such as in space or some other cryogenic environment. Recently, it was found that room temperature liquid metals (RTLM) such as gallium or its alloys could significantly reduce the electronics temperature compared with the conventional coolant, like water, oil or more organic fluid. However, most of the works were focused on RTLM which may subject to freeze under low temperature. So far, a systematic interpretation on the preparation and thermal properties of liquid metals under low temperature (here defined as lower than 0°C) has not yet been available and related applications in cryogenic field have been scarce. In this paper, to promote the research along this important direction and to overcome the deficiency of RTLM, a comprehensive evaluation was proposed on the concept of liquid metal with a low melting point below zero centigrade, such as mercury, alkali metal and more additional alloy candidates. With many unique virtues, such liquid metal coolants are expected to open a new technical frontier for heat transfer enhancement, especially in low temperature engineering. Some innovative ways for making low melting temperature liquid metal were outlined to provide a clear theoretical guideline and perform further experiments to discover new materials. Further, a few promising applied situations where low melting temperature liquid metals could play irreplaceable roles were detailed. Finally, some main factors for optimization of low temperature coolant were summarized. Overall, with their evident merits to meet various critical requirements in modern advanced energy and power industries, liquid metals with a low melting temperature below zero centigrade are expected to be the next-generation high-performance heat transfer medium in thermal managements, especially in harsh environment in space.

关键词： liquid metal     cryogenics     low melting point     thermal management     aircraft     liquid cooling     space exploration    

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Control division of agricultural non-point source pollution at medium-sized watershed scale in Southeast

HUANG Jinliang, HONG Huasheng, ZHANG Luoping

《环境科学与工程前沿（英文）》 2008年 第2卷 第3期   页码 333-339 doi: 10.1007/s11783-008-0035-7

摘要： This paper presents the study carried out for controlling agricultural non-point source pollution (NSP) in a medium-sized watershed covering 1.47 × 10 km in Southeast China using quantitative analysis coupled with geographic information system (GIS), universal soil loss equation (USLE), soil conservation service-curve number (SCS-CN), nutrient loss equations, and annualized agricultural nonpoint source model (AnnAGNPS). Based on the quantitative results derived from GIS and environmental models, five control division units were generated for NSP control in Jiulong River watershed, namely, controlling unit for soil losses, controlling unit for livestock breeding and soil losses, controlling unit for excessive fertilizer use and livestock breeding, controlling unit for soil losses and fertilizer use, and controlling unit for excessive fertilizer use and soil losses. This study proved that integrating GIS with environmental models can be adopted to efficiently evaluate major sources and contributors of NSP, and identify the critical source areas of NSP, which enables adjusting measures to local conditions by further control division units developed through such study for control and management of water quality degradation induced by NSP in the Jiulong River watershed.
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标题 作者 时间 类型 操作

Synthesis of mono and bis-4-methylpiperidiniummethyl-urea as corrosion inhibitors for steel in acidic

Abbas TEIMOURI, Nasrin SOLTANI, Alireza Najafi CHERMAHINI

期刊论文

Removing ammonia from air with a constant pH, slightly acidic water　spray wet scrubber using recycled

Ahmad Kalbasi Ashtari, Amir M. Samani Majd, Gerald L. Riskowski, Saqib Mukhtar, Lingying Zhao

期刊论文

Effective and selective separation of perrhenate from acidic wastewater by super-stable, superhydrophobic

期刊论文

A pyrazine based metal-organic framework for selective removal of copper from strongly acidic solutions

期刊论文

大中功率节能调速传动的合理电压等级

马小亮

期刊论文

Uncoupled state space solution to layered poroelastic medium with anisotropic permeability and compressible

Zhiyong AI, Wenze ZENG, Yichong CHENG, Chao WU

期刊论文

nsted acidic ionic liquids

Xiaomeng WANG, Mingjuan HAN, Hui WAN, Cao YANG, Guofeng GUAN

期刊论文

Improved CO

Mahboube Ghahramaninezhad, Fatemeh Mohajer, Mahdi Niknam Shahrak

期刊论文

Preparation of solar selective absorbing CuO coating for medium temperature application

HUANG Qunwu, WANG Yiping, LI Jinhua

期刊论文

Selective removal of iron(III) from highly salted chloride acidic solutions by solvent extraction using

Guoping Hu, Yue Wu, Desheng Chen, Yong Wang, Tao Qi, Lina Wang

期刊论文

Frontier of continuous structural health monitoring system for short & medium span bridges and condition

Ayaho MIYAMOTO, Risto KIVILUOMA, Akito YABE

期刊论文

大中型水利工程建设管理的实践和体会

张基尧

期刊论文

Electrolyzed water and its application in animal houses

Weichao ZHENG,Li NI,Baoming LI

期刊论文

Liquid metal as energy transportation medium or coolant under harsh environment with temperature below

Yunxia GAO, Lei WANG, Haiyan LI, Jing LIU

期刊论文

Control division of agricultural non-point source pollution at medium-sized watershed scale in Southeast

HUANG Jinliang, HONG Huasheng, ZHANG Luoping

期刊论文